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1
Material Balances Review
2
Gibbs Phase Rule
3
Lever Rule Derivation (P-x-y Diagram)
4
Phase Equilibrium: Txy Diagram
5
Pressure Effect on VLE
6
Condense a Binary Mixture
7
Fugacity Coefficients in VLE
8
Add Component to Binary VLE Mixture
9
Raoult's Law Explanation
10
Raoult's Law: Entropy Explanation
11
Add Non-Volatile Component to VLE System
12
Three-Component Solution Fugacities
13
Add One Component to Binary VLE System
14
Binary Vapor: Partial Condensation
15
Bubble Temperature Calculation
16
Bubble Temperature (Raoult's Law)
17
Bubble Temperature: Raoult's Law (POLYMATH Solution)
18
Bubble Point Calculation for Condenser
19
Dew Temperature Calculation/Excel Solver
20
Flash Calculation: Raoult's Law
21
Adiabatic Flash of Binary Liquid
22
Adiabatic Flash of Binary Liquid (Spreadsheet Solution)
23
Binary VLE
24
Energy to Evaporate Mixture
25
What is Fugacity in a Mixture?
26
What is Chemical Potential? (Single Component Systems)
27
What is Chemical Potential? (Multi-Component Systems)
28
Fugacity Temperature Dependence: Binary Mixture
29
Partial Molar Properties
30
Partial Molar Quantity
31
Mixing Ideal Solutions
32
Chemical Potential and Thermodynamic Activity
33
What is an Activity Coefficient?
34
Determine Bubble Pressure using a Margules Expression
35
Excess Gibbs Free Energy
36
Henry's Law
37
VLE Calculations with Margules Equation
38
Partial Molar Properties: Binary Solutions
39
Batch Distillation: Azeotrope
40
Osmotic Pressure Introduction
41
Osmotic Pressure Derivation
42
Molecular Weight of a Protein from Osmotic Pressure
43
Bubble Temperature: Non-Ideal Liquid
44
Bubble Temperature Non-Ideal Liquid/POLYMATH
45
Vapor-Liquid Equilibrium using the Wilson Equation
46
VLE using Wilson's Equation (POLYMATH)
47
Liquid-Liquid Equlibrium using UNIFAC
48
VLE Calculations with UNIFAC
49
VLLE for Immiscible Liquids
50
Phases for Immiscible Liquids
51
Partial Pressure: Immiscible Liquids
52
Vapor-Liquid-Liquid Equilibrium
53
Bubble Point Iteration
54
Calculate VLE Using an EOS
55
Calculate VLE using an EOS Spreadsheet
56
Calculate Fugacities of Mixtures using an EOS Spreadsheet
57
COSMOtherm: Pxy Diagram
58
COSMOtherm: Boiling Temperatures and Bubble Points
59
COSMOtherm: Activity Coefficients & Excess Gibbs Free Energy
60
Gibbs Free Energy Change for Non-Ideal Solution
61
Adiabatic Flash of Binary Liquid (POLYMATH Solution)
62
Phase Diagrams for Partially-Miscible Liquids
63
Introduction to Non-Ideal Solutions
64
Vapor-Liquid Equilibrium Ideal Solution
65
Define Bubble and Dew Points and Show on Graph
66
Using a Right Triangle, Ternary Phase Diagram
67
Gibbs Free Energy of Mixing and Liquid-Liquid Separation
68
Energy Balance for Adiabatic Evaporation of Water into a Vacuum
69
Release Gas from a Pressurized Tank
70
Osmotic Pressure for Nonideal Solutions
71
Calculate Molecular Weight from Osmotic Pressure for Nonideal Solution
72
Introduction to Solubility
73
Derive Equation for Boiling Point Elevation
74
Raoult's Law Example
75
Why a Solute Raises Boiling Point and Lowers Freezing Point
76
Partial Molar Volume Example
77
Determine Phase Composition and Amounts from Solid-Solid-Liquid Phase Diagram
78
Change in Chemical Potential for Component in Ideal Gas Mixture
79
Henry's Law Constant from Partial Pressure Data
80
Immiscible Liquid Phase Equilibrium Example
81
Isothermal Flash of a Ternary Mixture - Spreadsheet
82
Isothermal Flash of a Ternary Mixture
83
Vapor-Liquid-Liquid Equilibrium (Interactive Simulation)
84
P-x-y and T-x-y Diagrams for Vapor-Liquid Equilibrium (Interactive Simulation)
85
Bubble and Dew Points on P-x-y and T-x-y Diagrams (Interactive Simulation)
Description:
Explore fluid phase equilibria in mixtures through a comprehensive 7-hour video series. Delve into phase diagrams, Raoult's law, activity models, vapor-liquid-liquid equilibrium (VLLE), fugacity, and chemical potential. Learn to perform calculations for bubble and dew points, flash operations, and partial molar properties. Investigate non-ideal solutions, osmotic pressure, and the application of equations of state. Gain practical skills in using software tools like POLYMATH, Excel Solver, and COSMOtherm for thermodynamic calculations. Enhance understanding through interactive simulations and real-world examples, covering topics from basic concepts to advanced applications in chemical engineering thermodynamics.

Thermodynamics: Fluid Phase Equilibria in Mixtures

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