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1
Introduction
2
Main topic
3
Geometric picture
4
Topological changes
5
Droplet coalescence
6
Geometric representation
7
Ergotic theory
8
Nonergotic systems
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What if the ergotic hypothesis doesnt hold
10
Discontinuities
11
Spatial heterogeneity
12
Scaleconsistent thermodynamics
13
Deviation terms
14
Simple example
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More complicated example
16
Substituting thermal energy
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Maxwells demon
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Conservation of energy
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Relative permeability
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Energy barriers
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Diffusive length scale
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Energy conservation
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homogenization
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Darcys law
25
Crosscoupling terms
26
Simulations
27
Topology
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Pressure fluctuations
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Stationary vs nonstationary
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Summary
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Frequency dependence
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Maxwell demon
Description:
Save Big on Coursera Plus. 7,000+ courses at $160 off. Limited Time Only! Grab it Explore a 54-minute lecture on non-equilibrium theory for non-ergodic systems using time-and-space averaging. Delve into the development of a theoretical approach that assumes ergodic conditions only at very small length scales, applicable to many non-ergodic systems. Learn how fluctuations are constrained by internal energy dynamics and how quasi-ergodic requirements can identify valid transport coefficient timescales. Discover the application of this theory to immiscible fluid flow through porous media, explaining non-Gaussian pressure fluctuations caused by capillary events. Understand how macroscopic dynamics can be homogenized by choosing appropriate averaging timescales and how fluid topology changes contribute to non-ergodic effects. Examine the role of time-and-space averages in accounting for discrete changes based on topological residence time. Cover topics such as geometric representation, ergodic theory, scale-consistent thermodynamics, conservation of energy, relative permeability, Darcy's law, and pressure fluctuations in this comprehensive exploration of non-equilibrium thermodynamics for non-ergodic systems. Read more

Non-equilibrium Theory for Non-ergodic Systems Based on Time-and-Space Averaging

PoreLab
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